【摘要】 以Span-60为乳化剂、双氧水为氧化剂、固载磷钨酸的半焦为催化剂,对流化催化裂化(FCC)柴油进行氧化脱硫;考察了反应时间、反应温度、Span-60乳化剂用量和双氧水用量对脱硫率的影响。实验结果表明,FCC柴油氧化脱硫的优化反应条件为:反应时间60m in、反应温度60℃、Span-60乳化剂用量(基于FCC柴油的质量分数)0.6%、双氧水用量(基于FCC柴油的质量分数)2%、催化剂用量(基于FCC柴油的质量分数)1.2%。在此条件下对FCC柴油进行氧化脱硫,FCC柴油中的硫含量由1 400μg/g降至84μg/g,脱硫率达94%。气相色谱分析结果显示,氧化脱硫后FCC柴油中的苯并噻吩衍生物、二苯并噻吩及其衍生物基本上被脱除。更多还原

【Abstract】 Oxidative desulfurization of fluid catalytic cracking(FCC) diesel was investigated by using Span-60 as emulsifier,hydrogen peroxide as oxidant and phosphotungstic acid/semi-coke as catalyst.Effects of reaction time,reaction temperature,emulsifier dosage and oxidant dosage on desulfurization rate were studied.Under optimal reaction conditions: reaction time 60 min,reaction temperature 60 ℃,mass fraction of Span-60 emulsifier 0.6%(based on FCC diesel),mass fraction of oxidant 2%(based on FCC diesel) and mass fraction of catalyst 1.2%(based on FCC diesel),sulfur content in FCC diesel could be lowered from 1 400 μg/g down to 84 μg/g with desulfurization rate of 94%.According to analysis of FCC diesel by GC before and after oxidation and desulfurization,the removals of benzothiophene derivatives,dibenzothiophene and derivatives were almost complete.更多还原