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间二甲苯氨氧化催化剂工业化改进试验研究
Study on the improvement of m-xylene ammoxidation catalyst
【摘要】 以扩孔、灼烧后的改性硅胶作为载体,将含有V、Cr、Mo、P、K的活性组份物均匀浸渍于载体上,得到V-Cr-Mo-P-K系间二甲苯氨氧化催化剂(NT08#),在100 t/a间苯二甲腈中试装置进行生产试验,流化反应床特征反应温度(浓2#)390~400℃,投料比(摩尔比)空气∶氨∶间二甲苯=38∶7∶1,产品收率达到了91.3%。
【Abstract】 Using the improved silica gel as carrier,dipping the multiple active ingredients which included V,Cr,Mo,P,K components in the carrier,then the V-Cr-Mo-P-K series m-xylene ammoxidation catalyst(NT08#) were obtained.The productive experiment was carried on the 100 t/a isophthalonitrile produce line,the characteristic reaction temperature of the fluid-bed reactor was 390~400 ℃,the material molar ratio of air ∶ammonia ∶m-xylene was 38 ∶7 ∶1.The result showed that the yield of isophthalonitrile could reach 91.3%.
- 【文献出处】 应用化工 ,Applied Chemical Industry , 编辑部邮箱 ,2009年08期
- 【分类号】TQ246
- 【被引频次】2
- 【下载频次】209