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琼东南盆地与甲烷渗漏有关的早期成岩作用和孔隙水化学组分异常

Early diagenesis records and chemical composition abnormalities in pore water for methane-seep in sediments from the southern Qiongdong Basin

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【作者】 邬黛黛叶瑛吴能友蒋宏晨季珊珊董海良刘坚

【Author】 WU Dai-dai1,2,3,YE Ying2,WU Neng-you1,3,5,JIANG Hong-chen4,JI Shan-shan4,DONG Hai-liang4,LIU Jian5(1.Key Laboratory of Renewable Energy and Gas Hydrate of Guangzhou Institute of Energy Conversion of Chinese Academy of Sciences,Guangzhou Energy Institute,Chinese Academy of Sciences,Guangzhou 510640,China;2.Department of Earth Sciences,Zhejiang University,Hangzhou 310027,China;3.Guangzhou Center for Gas Hydrate Research,Chinese Academy of Sciences,Guangzhou 510640,China;4.Department of Geology,Miami University,Oxford 45056,USA;5.Guangzhou Marine Geological Survey Bureau,Ministry of Land and Natural Resources,Guangzhou 510075,China)

【机构】 中国科学院广州能源研究所中国科学院可再生能源与天然气水合物重点实验室浙江大学地球科学系中国科学院广州天然气水合物研究中心国土资源部广州海洋地质调查局美国迈阿密大学地质系

【摘要】 X-射线衍射和扫描电镜观察表明,采自南海北部琼东南盆地的沉积物样品中有天然气水合物和甲烷渗漏指示意义的自生碳酸盐、硫酸盐和草莓状framboids黄铁矿,自生矿物组合和显微结构特征与冷泉沉积物类似,属微生物成因。沉积物孔隙水化学组分分析结果显示,随着埋藏深度加深,SO42-,Ca2+,Mg2+和Sr2+浓度明显降低,Mg2+浓度与Ca2+浓度和Sr2+浓度与Ca2+浓度的比值急剧增加,这些地球化学特征与世界上天然气水合物产区的浅表层沉积物孔隙水中离子浓度异常吻合较好,暗示采样站位深部可能有油气或天然气水合物藏。

【Abstract】 Complicated authigenic minerals were identified by XRD and SEM in the study sediment samples from the southern Qiongdong Basin,the northern South China Sea,such as miscellaneous carbonate,sulphate and frambiodal pyrite,which consistently indicate the gas hydrate and methane seep to occur in the area.The assemblage and fabric features are similar to those being found in cold-seep sediments,which are thought to be related to microorganisms fueled by dissolved methane.Results of chemical composition analysis in the pore water of the sediment samples show that the concentrations of SO2-<sub>4,Ca2+,Mg2+ and Sr2+ decrease clearly,and the concentration ratios of Mg2+ to Ca2+ and Sr2+ to Ca2+ increase sharply as the depth increases.These geochemical characteristics are similar to chemical composition abnormalities in the pore water of the shallow sediments where the gas hydrate occurs in the world.Those results strongly indicate that there should be gas hydrates or deep water oil(gas) reservoirs underneath.

【基金】 中国科学院广州能源研究所所长创新基金项目资助(o807r71001);国家重点基础研究计划资助(2009CB219506);国家高技术研究发展计划“八六三”计划资助(2006AA09Z216)
  • 【文献出处】 海洋学报(中文版) ,Acta Oceanologica Sinica , 编辑部邮箱 ,2009年02期
  • 【分类号】P744.4
  • 【被引频次】19
  • 【下载频次】551
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