节点文献
金属铜铅锌铝离子与乙二醇的络合行为
Complexation Behaviors of Different Metal Ions with Ethylene Glycol
【摘要】 采用酸碱滴定法研究铜、铅、锌、铝离子与乙二醇的络合作用,并利用计算机软件MEDUSA模拟出它们的络合常数;试验结果表明乙二醇和铜、铅、锌离子之间的络合作用较弱,属物理作用范畴;而乙二醇和A l3+作用较铜、铅、锌离子为强,可生成一种新的沉淀物。
【Abstract】 The complexation of Cu2+,Pb2+,Zn2+,Al3+ with ethylene glycol was studied by potentiometric titration.MEDUSA,a computer software,was used to simulate the coordination constants of Cu2+,Pb2+,Zn2+,Al3+ with ethylene glycol,respectively.The results show that the reaction of Cu2+,Pb2+,Zn2+ with ethylene glycol was weak physical interaction,and the reaction of ethylene glycol with Al3+ was strong enough to form a new precipitate.
【关键词】 酸碱滴定;
金属离子;
乙二醇;
MEDUSA;
络合;
【Key words】 potentiometric titration; metal ions; ethylene glycol; MEDUSA; complexation;
【Key words】 potentiometric titration; metal ions; ethylene glycol; MEDUSA; complexation;
【基金】 国家自然科学基金(20677022);国家自然科学重点基金(20537020)
- 【文献出处】 济南大学学报(自然科学版) ,Journal of University of Jinan(Science and Technology) , 编辑部邮箱 ,2009年01期
- 【分类号】O621.1
- 【被引频次】8
- 【下载频次】509