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用于氨和轻烃SCR脱硝的催化剂研究进展

RESEARCH ACHIEVEMENTS OF CATALYSTS FOR SCR DENITRIFICATION BY NH3 AND HYDROCARBON

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【作者】 李玉然杨立寨由长福祁海鹰

【Author】 LI Yu-ran,YANG Li-zhai,YOU Chang-fu,QI Hai-ying Key Laboratory for Thermal Science and Power Engineering under Educational Ministry,Qinghua University,Beijing 100084,PRC

【机构】 清华大学热科学与动力工程教育部重点实验室

【摘要】 制约我国燃煤NOx排放控制的主要因素是用于选择性催化还原(SCR)的催化剂成本和潜在的重金属二次污染问题。为此,分别论述了用于氨和轻烃选择性催化还原NOx的金属氧化物、金属离子交换沸石、钛柱撑粘土、Al2O3担载重金属、稀土氧化物等催化剂的研究进展,包括催化剂的选择原则、反应机理、催化活性及活性温度区间、烟气中HO和SO的影响等,总结了进一步改进催化活性的方向。

【Abstract】 The main factors restricking the application of Selective Catalytic Reduction (SCR) technology in China to control NOx emission are the problems of catalyst cost for SCR denitrification and the potential secondary pollution of heavy metalls.For this reason,the research achivements for catalysts of SCR denitrifucation by NH3 and hydrocarbon have been expounded respectively,such as metal oxides,metal ion exchanged zeolites,titanium pillared clay,Al2O3 supported heavy metalls,and rare earth oxides catalysts,and including principles of selecting a suitable catalyst,reation mechanism,catalytic activity,temperature range of activity,and effects of H2O and SO2 in the flue gas etc.,and direction for further improving catalytic activities being proposed.

【基金】 国家重点基础研究“973”计划资助项目(2006CB200305)
  • 【文献出处】 热力发电 ,Thermal Power Generation , 编辑部邮箱 ,2009年04期
  • 【分类号】X701
  • 【被引频次】4
  • 【下载频次】298
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