【摘要】 首次以乙酸锌、三(2-氨基乙基)胺及四氟硼酸钠为原料在甲醇介质中反应,合成得到了新颖桥联配合物{[(tren)Zn(CH3COO)Zn(tren)](BF4)3},用元素分析、红外光谱、核磁共振氢谱和热重分析对其进行了表征,用X-射线单晶衍射仪测定了其晶体结构,其晶体属于四方晶系,空间群为P-42(1)m,晶体参数分别为a=1.16106(19)nm,b=1.16106(19)nm,c=1.0851(3)nm,α=β=γ=90°,V=1.4627(6)nm3;Dc=1.686 g/cm3;Z=3;F(000)=756;μ=1.745 mm-1。更多还原

【Abstract】 Based on the reaction of zinc acetate,sodium tetrafluoroborate and tren(where tren is tris(2-aminoethyl) amine) in methanol medium,a new acetate bridged complex {[(tren)Zn(CH3COO)Zn(tren)](BF4)3} was synthesized.It’ s structure and thermal properties were characterized by elemental analysis,IR spectrum,1H-NMR and TG.The crystal structure of the compound C14H20N6 was also determined by X-ray single crystal diffraction.The crystal belongs to crystal tetragonal system with space group P-42(1)m,and crystallographic data of the compound are: a=1.16106(19) nm,b=1.16106(19) nm,c= 1.0851(3) nm,α=β=γ=90°,V=1.4627(6) nm3,Dc =1.686 g/cm3,Z= 3,F(000)= 756,μ=1.745 mm-1.更多还原