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共焦显微拉曼在司法鉴定中甄别印章的应用

Application of Confocal Micro-Raman for Identification of Ink Marks in Judicial Authentication

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【作者】 籍康赵杰高蓉衡航

【Author】 Ji Kang 1,Zhao Jie 2,Gao Rong 3,Heng Hang 1(1. Jiangsu Provincial Key Lab for Photoelectric Technology,Analysis and Testing Center,Nanjing Normal University,Nanjing 210097,China)(2. School of Law,Nanjing Normal University,Nanjing 210097,China)(3. School of Physics and Technology,Nanjing Normal University,Nanjing 210097,China)

【机构】 南京师范大学分析测试中心江苏省光电技术重点实验室南京师范大学法学院南京师范大学物理科学与技术学院

【摘要】 利用共焦显微拉曼光谱技术,以红外激光785nm作激发光源,对几种不同品牌的印泥、印油和打印油分别做了拉曼光谱图.结果表明:印泥、印油含酯类物质,在拉曼光谱上有1235cm-1特征峰;彩色喷墨打印油含醇类物质,在拉曼光谱上有1086cm-1的特征峰.借此,可用拉曼光谱来区分印泥、印油与打印油.此外,不同品牌印泥、印油和打印油的拉曼光谱都有各自的特征峰,利用这些特征峰可以准确地辨别出印泥、印油的品牌或判断印章是否为伪造.共焦显微拉曼光谱技术为司法鉴定中如何鉴别文书中伪造印章,提供了一种快速、便捷、准确、无损的检测方法.

【Abstract】 Taking advantage of Confocal Micro-Raman technology,several commercial inkpads,stamp-pad ink and printing ink are studied by the IR (785 nm) laser. The results show that inkpads and stamp-pad ink have the 1 235 cm -1 characteristic peak on the Raman spectra because of containing the ester,while printing ink has 1 086 cm -1 characteristic peak because of containing the alcohol material. This difference can be used to identify the counterfeit copies recorded with printing ink from those recorded with inkpads and the stamp-pad ink. Furthermore,different brands inkpads,stamp-pad ink and printing ink have the different characteristic peaks on the Raman spectra,so the brands of ink and the copies can be distinguished easily. Confocal Micro-Raman technology provide a scientific method to judge the evidence of ink marks in the area of judicial authentication.

【关键词】 拉曼光谱印迹无损检测
【Key words】 Confocal Micro-Ramaninknon-destructive detection
【基金】 国家自然科学基金(20603018)资助项目
  • 【文献出处】 南京师大学报(自然科学版) ,Journal of Nanjing Normal University(Natural Science Edition) , 编辑部邮箱 ,2009年03期
  • 【分类号】D918.2
  • 【被引频次】17
  • 【下载频次】365
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