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炼焦煤中多环芳烃的分布特性研究
DISTRIBUTION CHARACTERISTIC OF POLYCYCLIC AROMATIC HYDROCARBONS IN COKING COAL
【摘要】 选取6种典型炼焦煤用二氯甲烷作萃取剂经索氏提取和K-D浓缩,采用硅胶柱层析纯化,利用高效液相色谱法(HPLC)对其中含有的16种多环芳烃(PAHs)进行测定,研究了不同煤种中PAHs的分布.结果表明,6种煤中PAHs主要以3环、4环和5环形式存在;此外还发现PAHs总量随煤化度提高而减少,随挥发分含量和氢碳摩尔比增大而增加;且PAHs含量与煤中碳含量和氧碳摩尔比也存在一定关系.
【Abstract】 The distribution characteristics of 16 polycyclic aromatic hydrocarbons(PAHs)in 6 typical coking coals were investigated.The coal samples were extracted by the Soxhlet extractor with methylene chloride,concentrated by the K-D concentrator,and purified by silica gel technique,then PAHs in the coal samples were analyzed by a high performance liquid chromatographic(HPLC).Experimental results showed that most PAHs were present in the coal with 3-ring to 5-ring structure in the six coals;moreover,the higher coal rank is,the lower the total content of PAHs is.The coal with the high volatile content and H/C mole ratio contained higher PAHs.It was also discovered that there was correlation between PAHs content and carbon content,O/C mole ratio in the six coals.
- 【文献出处】 煤炭转化 ,Coal Conversion , 编辑部邮箱 ,2009年04期
- 【分类号】TQ533.1
- 【被引频次】8
- 【下载频次】234