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焦炭高温热膨胀性能研究

STUDY ON THERMAL EXPANSION OF COKE

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【作者】 刘晓辉秦延军张琢吴信慈张睿凌立成杨俊和

【Author】 Liu Xiaohui1,2 Qin Yanjun1,2 Zhang Zhuo2 Wu Xinci2 Zhang Rui1Lin Licheng1 and Yang Junhe2(1.Unilab,State Key Laboratory of Chemical Engineering,East China University of Science and Technology,200237 Shanghai;2.Department of Materials Science and Engineering,Shanghai Institute of Technology,200235 Shanghai)

【机构】 华东理工大学联合化学反应研究所国家重点实验室上海应用技术学院

【摘要】 以8种不同种类单种煤焦炭为原料,在氮气气氛下,测定了30℃~1300℃范围内的焦炭热膨胀性能.依据焦炭自身的特性,提出了适合焦炭的热膨胀性能测定方法和热膨胀性能参数.根据测得的焦炭热膨胀性能参数,探索了焦炭热膨胀性能、焦炭热强度及煤变质程度之间的关系.研究发现,依据所提出的参数可以将焦炭热膨胀性能分为三个阶段,并且提出了焦炭收缩阶段为微裂纹产生的观点.在焦炭热膨胀对热强度影响方面,发现热膨胀性能参数与焦炭热强度成正比关系.在煤的变质程度对焦炭膨胀性能影响方面,发现最大线性膨胀Lf与挥发分Vdaf成二次曲线关系,在Vdaf为30%左右Lf取到最大值.最大线性膨胀Lf与煤的黏结性成正比关系,但是会受到挥发分的影响.

【Abstract】 The thermal expansion of 8 different coke was measured between 30 ℃-1 300 ℃ in N2.Based on coke’s own characteristics,the parameter and measurement of coke expansion are given.Based on parameter measured,this paper explores the relationship between the expansion of coke and CSR,CRI,coal.Through research the result shows:1)the thermal expansion of coke can be divided into three stages and pointing out the shrinkage stage means micro-cracks generating.2)The parameters of thermal expansion are increasing with the increasing of coke heat strength.3)The relation between Lf and Vdaf is quadratic function.When Vdaf comes up to 30%,the Lf can get maximum.Lf is increasing with the increasing of Bond of coal,but which is affected by Vdaf.

【关键词】 焦炭膨胀热应力反应性反应后强度
【Key words】 cokethermal expansionshrinkageCRICSR
【基金】 国家自然科学基金资助项目(50473064,50730003,50672025,50773040);上海科委资助项目(065212048,06DZ22003,2006JC14018);上海市重点学科资助项目(P1502)
  • 【分类号】TQ520.1
  • 【被引频次】4
  • 【下载频次】249
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