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[Ni（H₂O）₆][C₁₀H₆O₆S₂]的合成及晶体结构

Synthesis and Crystal Structure of the Complex [Ni（H₂O）₆](C₁₀ H₆O₆S₂)

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【Author】 HAN Min-le 1, ZHANG Gui-ying 1, LI Hua-bing 1, PAN Han-xiao 2(1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China; 2. People’s liberation Army, Unit No. 96275 Luoyang 471003, China)

【机构】洛阳师范学院化学化工学院；解放军96275部队；

【摘要】本文合成了1,5-萘二磺酸合镍(Ⅱ)配合物,并通过X-射线单晶衍射测定了其晶体结构.配合物晶体属单斜晶系,P21/c空间群,晶胞参数:a=13.2592(16),b=6.6503(8)　,c=9.6361(12),β=92.0400(10)°,V=849.15(18)3,Z=2,F(000)=468,Dc=1.772g·cm-3,Mr=453.07,μ(Mo Kα)=1.449cm-1.配合物由阳离子基团和阴离子基团构成,阳离子基团为Ni(Ⅱ)离子和六个水分子配位基团,为八面体几何构型,阴离子基团是1,5-萘二磺酸根离子,它们通过氢键形成三维结构.更多还原

【Abstract】 1,5-naphthalene-disulfonate nickel(Ⅱ) complex has been synthesized and structure determined by X-ray diffraction method. As the data indicate, its crystal belongs to monoclinic system with space group C2, a=13.2592 (16),b =6.6503(8),c =9.6361(12), β =92.0400(10)°, V =849.15(18)3 , Z =2, F (000)=468, D c=1.772 g·cm -3 , M r=453.07, μ (Mo K α)=1.449 cm-1·O-H…O hydrogen-bonding interactions generate a three-dimensional architecture.更多还原