【摘要】 在恒定葡萄糖质量分数w=10%,应用经典电动势方法测定无液接电池的电动势:Pt,H2(101.325kPa)|HCl(m),C6H12O6(w),H2O(1-w)|AgCl-Ag根据测得该电池的电动势,确定了混合溶液中AgCl-Ag电极的标准电极电势,讨论了盐酸的迁移性质.更多还原

【Abstract】 The Apparent thermodynamic properties of HCl-glucose-H2O system were studied by means of emf measurements of the cell without liquid junctionPt,H2(101.325kPa)│HCl(m),C6H12O6(w),H2O(1-w)│AgCl-Agat the mass fraction of glucose w=10% in the mixed solution,from 278.15 to 318.15 K for cell.The standard electrode potential of AgCl-Ag in the mixed solution has been determined from thevalues of emf.The standard transfer Gibbs free energies,transfer entropy,and transfer enthalpy of HCl have been calculated.更多还原