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State of water and its implications for supersaturated structures in Mg(NO32 aerosols

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【Author】 ZHAO LiJun1,2, ZENG QingXuan2 & ZHANG YunHong1 1 The Institute of Chemical Physics, Beijing Institute of Technology, Beijing 100081, China 2 School of Aerospace Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

【摘要】 One technique based on the difference spectra was developed to study the state of water in supersaturated Mg(NO3)2 aerosols. The technique could be derived from the observation that the Raman scattering and infrared absorbance cross sections of molecular vibrations of interest remain practically constant from diluted solutions to supersaturated aerosols. The spectra of solvated water were obtained and primarily related to the first hydration layers of solute molecules in supersaturated Mg(NO3)2 aerosols. Based on this investigation, a chain structure was proposed to occur in the supersaturated Mg(NO3)2 aerosols at low relative humidities (RHs).

【Abstract】 One technique based on the difference spectra was developed to study the state of water in supersaturated Mg(NO3)2 aerosols. The technique could be derived from the observation that the Raman scattering and infrared absorbance cross sections of molecular vibrations of interest remain practically constant from diluted solutions to supersaturated aerosols. The spectra of solvated water were obtained and primarily related to the first hydration layers of solute molecules in supersaturated Mg(NO3)2 aerosols. Based on this investigation, a chain structure was proposed to occur in the supersaturated Mg(NO3)2 aerosols at low relative humidities (RHs).

【基金】 Supported by National Natural Science Foundation of China (Grant Nos. 20673010 and 20640420450);“111” Project (Grant No. B07012);China Postdoctoral Science Foundation (Grant No. 20070410466)
  • 【文献出处】 Chinese Science Bulletin ,科学通报(英文版) , 编辑部邮箱 ,2009年02期
  • 【分类号】O414.13
  • 【下载频次】39
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