Hydrothermal Synthesis, Crystal Structure and Magnetic Property of a Novel Pentanuclear Copper（II） Complex:[Cu₅（SIP）₂（HSIP）₂（H₂O）₁₈]（H₂O）₅

【摘要】 The pentanuclear complex, Cu5(SIP)2(HSIP)2(H2O)18(H2O)5(H3SIP = 5-sulfoi-sophthalic acid), has been synthesized by the hydrothermal reaction of CuCl2 with NaH2SIP at 160 ℃, and characterized by single-crystal X-ray diffraction and IR spectrum.The crystal of the complex crystallizes in a triclinic system, space group P1-, with a = 7.0018(5), b = 11.9725(8), c = 19.0424(13) , α = 78.8540(10), β = 85.1710(10), γ = 83.6080(10)o, V = 1553.24(19) 3, Z = 1, C32H60O51S4Cu5, Mr = 1706.74, Dc = 1.825 g/cm3, μ = 1.937 mm-1, F(000) = 869, the final R = 0.0709 and wR = 0.1503 for 4235 observed reflections with I > 2σ(I).The five Cu2+ ions are connected by two symmetry-related tridentate SIP3-ligands and charge-balanced by two monodentate HSIP2-ligands, giving a discrete pentanuclear structure.The pentanuclear copper molecules are linked by hydrogen bonds to form a three-dimensional supramolecular structure.The temperature-dependent magnetic susceptibility data revealed weak ferromagnetic magnetic interactions between the Cu2+ ions.更多还原

【Abstract】 The pentanuclear complex, Cu5(SIP)2(HSIP)2(H2O)18(H2O)5(H3SIP = 5-sulfoi-sophthalic acid), has been synthesized by the hydrothermal reaction of CuCl2 with NaH2SIP at 160 ℃, and characterized by single-crystal X-ray diffraction and IR spectrum.The crystal of the complex crystallizes in a triclinic system, space group P1-, with a = 7.0018(5), b = 11.9725(8), c = 19.0424(13) , α = 78.8540(10), β = 85.1710(10), γ = 83.6080(10)o, V = 1553.24(19) 3, Z = 1, C32H60O51S4Cu5, Mr = 1706.74, Dc = 1.825 g/cm3, μ = 1.937 mm-1, F(000) = 869, the final R = 0.0709 and wR = 0.1503 for 4235 observed reflections with I > 2σ(I).The five Cu2+ ions are connected by two symmetry-related tridentate SIP3-ligands and charge-balanced by two monodentate HSIP2-ligands, giving a discrete pentanuclear structure.The pentanuclear copper molecules are linked by hydrogen bonds to form a three-dimensional supramolecular structure.The temperature-dependent magnetic susceptibility data revealed weak ferromagnetic magnetic interactions between the Cu2+ ions.更多还原