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Two novel interpenetrated zinc(Ⅱ) and cadmium(Ⅱ) coordination polymers based on 4-imidazole-benzoate:Syntheses,crystal structures and properties

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【Author】 BAI ZhengShuai,CHEN ShuiSheng,ZHANG ZhengHua,CHEN ManSheng,LIU GuangXiang & SUN WeiYin State Key Laboratory of Coordination Chemistry,Institute of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China

【摘要】 Two novel interpenetrated coordination polymers,[Zn(IBA)2]n (1) and {[Cd(IBA)2(H2O)].4H2O}n (2),have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal con-ditions. Complex 1 crystallizes in a chiral space group and has a two-fold interpenetrated 2D network structure with (4,4) topology,while complex 2 is a 3D porous dia network with four nets interpene-trating each other. The SHG activity of 1 and the photoluminescent property of 2 have been investi-gated.更多还原

【Abstract】 Two novel interpenetrated coordination polymers,[Zn(IBA)2]n (1) and {[Cd(IBA)2(H2O)].4H2O}n (2),have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal conditions. Complex 1 crystallizes in a chiral space group and has a two-fold interpenetrated 2D network structure with (4,4) topology,while complex 2 is a 3D porous dia network with four nets interpene-trating each other. The SHG activity of 1 and the photoluminescent property of 2 have been investigated.更多还原

【关键词】 coordination polymer； interpenetration； crystal structure； photoluminescence property；
【Key words】 coordination polymer； interpenetration； crystal structure； photoluminescence property；

【基金】 Supported by the National Natural Science Foundation of China (Grant Nos. 20731004 & 20721002);the National Basic Research Program of China (Grant No. 2007CB925103)

【文献出处】 Science in China(Series B:Chemistry) ,中国科学(B辑:化学)(英文版) , 编辑部邮箱 ,2009年04期

【分类号】O634
【被引频次】6
【下载频次】51

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