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低碳钢中AlN和BN竞相析出热力学分析

Thermodynamic Analysis of AlN and BN Competitive Precipitation in Low Carbon Steel

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【作者】 李培松肖丽俊谢植

【Author】 LI Pei-song1,XIAO Li-jun2,XIE Zhi1(1.School of Information Science and Engineering,Northeastern University,Shenyang 110004,Liaoning,China;2.State Key Laboratory of Advanced Steel Processes and Products,Central Iron and Steel Research Institute,Beijing 100081,China)

【机构】 东北大学信息科学与工程学院钢铁研究总院先进钢铁流程及材料国家重点实验室

【摘要】 微合金元素硼已广泛应用于硅钢、软钢等钢中,而硼对其作用的机理是与钢中AlN和BN的竞相析出紧密相关的。根据AlN和BN在钢中的固溶度积公式推导了钢中AlN和BN的析出量与温度之间的关系,分析和讨论了典型加硼低碳铝镇静钢中AlN、BN的竞相析出关系,研究结果表明即使加入极微量的微合金元素硼(0.001%),钢中BN的开始析出温度即可高于AlN,从而表现为BN优先析出,部分抑制AlN的析出。

【Abstract】 Microalloying element boron has been widely applicated in silicon steel and mild steel,and the relationship between AlN and BN precipitation has the mainly effect on the property of such steels.Based on solubility product of AlN and BN in low-C Al-killed steel,the relationship between amount of AlN and BN precipitation and temperature in steel is deduced.Additionally,the competition of AlN precipitation with BN precipitation in typical Al-killed steel is analyzed and discussed.The research results showed that when more than 0.001% B was added to the low-C Al-killed steel,the BN precipitation will be prior to AlN precipitation,and partly restrain the AlN precipitation.

【关键词】 AlNBN竞相析出
【Key words】 AlNBNcompetition precipitation
【基金】 国家重点基础研究发展规划资助项目(2004CB619107)
  • 【文献出处】 钢铁研究学报 ,Journal of Iron and Steel Research , 编辑部邮箱 ,2009年05期
  • 【分类号】TG142.31
  • 【被引频次】33
  • 【下载频次】803
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