【摘要】 采用顶空气相色谱法对焦化厂附近不同距离采集的土壤样品中苯含量进行了检测,分析了气象、地理位置等因素对苯含量的影响。结果表明,苯浓度值大小为南>北>东>西,在距离焦化厂200m左右处出现最大值,检测结果与当地风向(主导风向为南风)具有较好的相关性;采用大气污染扩散模型对焦化厂附近空气中的苯浓度和最大落地距离进行了计算,结果与土壤中苯的检出规律具有一致性。通过呼吸暴露法对焦化区居民进行了健康风险和泄漏风险评价结果表明,焦化厂的苯产生源直接排放会对附近居民造成严重的安全隐患(Risk=0.008,略小于警戒线0.01),而经过治理后对当地居民造成的致癌风险会大大减小(Risk=0.001);发生苯泄漏时,在E-F稳定度下,距离焦化区最近的村庄1处的浓度值超过中国居住区大气中有毒物质的最高允许浓度11.7倍,具有较大的风险性。更多还原

【Abstract】 Head space chromatography was applied to the determination of benzene collected from different distance of coking suburbs soil,studied the factors that enters into the results.The result indicates that there is very strong positive relationship between orientation and benzene concentration,the results was: south >west >north >east.And the maximum was appeared about 200m off the Coking & Chemical Factory;and the benzene concentration of ambient air in the vicinity of coking suburbs was calculated by atmosphere diffused mode,the results was consistent with the examined disciplinarian.We also estimated the healthy state by breath exposure model.Results demonstrated that the incidence of the cancer risk will greatly diminished after dealing with the source of benzene.Under the E-F stability circumstances,if the leaks of benzene happen,residential area1 will of great risks.更多还原