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水杨醛缩2-芴胺席夫碱的合成、晶体结构及生物活性
Synthesis,crystal structure and biological activity of salicylaldehyde-fluoreylamine Schiff base
【Abstract】 The synthesis of a new Schiff base(salicylaldehyde-fluorenylamine) with fluorene was reported.The molecular structure was characterized by IR,1H NMR,MS and elementary analysis.The crystal structure was determined by X-ray diffraction method.The crystal belongs to monoclinic,space group P2(1)/c with a =1.60170(6)nm,b=0.82261(8)nm,c=1.11693(2)nm,β=96.671(7)°,V= 1.4617(2) nm3,Z=4,Dc = 1.297g/cm3,μ(MoKα) = 0.080mm-1,F(000) = 600,R1= 0.0857,WR2= 0.1989.The biological activity test indicated that it was an effective bactericide on bacillus such as Staphylococcus aureus,Bacillus thuring Iensis and Bacillus subtilis.
【关键词】 水杨醛;
2-芴胺;
席夫碱;
晶体结构;
生物活性;
【Key words】 salicylaldehyde; 2-fluoreylamine; Schiff base; crystal structure; biological activity;
【Key words】 salicylaldehyde; 2-fluoreylamine; Schiff base; crystal structure; biological activity;
【基金】 黄石理工学院科研项目(08yjz27B)资助
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2009年11期
- 【分类号】O621.13
- 【被引频次】11
- 【下载频次】234