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Keggin和Dawson结构多金属氧酸盐光催化脱色偶氮染料

Decolourization of azo dyes by photocatalyzing of polyoxometalates with Keggin and Dawson structure

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【作者】 马凤霞刘坤孟凡霞陈亚光徐文娟

【Author】 MA Feng-xia1,2,LIU Kun3,MENG Fan-xia4,CHEN Ya-guang1,XU Wen-juan 1(1.Faculty of Chemistry,Northeast Normal University,Changchun 130024,China;2.Department of Arts and Science,Jilin Agricultural Science and Technology College,Jilin 132101,China;3.Changchun NO.2 Senior School,Changchun 130061,China;4.Ji`an NO.1 Senior School,Ji`an 134200,China)

【机构】 东北师范大学化学学院吉林农业科技学院文理学院长春市第二中学集安市第一中学

【Abstract】 The investigation photocatalytic degradation of three azo dyes solution(Acid Mordant Navy Blue RRN,Acid Mordant Black PV,Acid Mordant Brown RH) under UV light irradiation using the polyoxometalates as catalyst was reported in this article.The research results showed that the photocatalytic activity of Keggin catalyst is higher than that of Dawson,and the catalyst α-H4SiW12O40 had the best efficiency to the photocatalytic decoloration of RRN.In 350 mg·L-1(30 mL) RRN solution,the optimum reaction condition was as follow:the amount of catalyst α-H4SiW12O40 is 75 μmol·L-1,V(methanol)=3.0 mL,pH=3.0.Under the above condition,the decolorization rate of RRN at 40 minutes comes up to 98.66%.

  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2009年07期
  • 【分类号】TQ610.9
  • 【被引频次】34
  • 【下载频次】268
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