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一个被席夫碱配体支撑的一维梯形水簇Bpcmda·4H2O的合成和表征
Synthesis and crystal structure of one dimensional water ladders supported by a schiff-base ligand Bpcmda·4H2O
【摘要】 合成了化合物Bpcmda.4H2O,利用IR、元素分析、1HNMR和单晶X-射线衍射进行了表征。详细的结构分析表明Bpcmda.4H2O中的溶剂水分子以O-H…O氢键的相互作用形成了一个沿着b轴伸展的独一无二的梯形水簇。
【Abstract】 The title compound Bpcmda·4H2O has been synthesized and characterized by IR,elemental analysis,1H NMR and single crystal X-ray diffraction.Detailed structure analysis revealed that the solvated water molecules in Bpcmda 4H2O involved in intermolecular O-H…O hydrogen bonds to give a unique water ladder running along the crystallographic b axis.
【关键词】 水簇合物;
席夫碱配体;
联吡啶衍生物;
晶体结构;
【Key words】 water cluster; schiff-base ligand; dipyridyl derivative; crystal structure; synthesis;
【Key words】 water cluster; schiff-base ligand; dipyridyl derivative; crystal structure; synthesis;
【基金】 盐城师范学院自然科学研究项目资助
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2009年06期
- 【分类号】O621.1
- 【下载频次】75