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Sol-Gel法制备La3+改性的TiO2纳米粉体

Synthesis of La3+-modified TiO2 nanopowders via sol-gel method

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【作者】 王丹军郭莉李东升付峰韦庆婷史启祯

【Author】 WANG Dan-jun1,Guo Li1,LI Dong-sheng1,*,FU Feng1,WEI Qin-ting1,SHI Qi-zhen2(1.College of Chemistry &Chemical Engineering,Yan’an University,Shaanxi Key Laboratory ofChemical Reaction Engineering,Yan’an 716000,China;2.Department of Chemistry,Northwest University,Shaanxi Key Laboratory ofPhysico-Inorganic Chemistry,Xi’an 710069,China)

【机构】 延安大学化学与化工学院陕西省化学反应工程重点实验室西北大学化学系陕西省物理无机重点实验室

【Abstract】 La-doped TiO2 nanopowders were synthesized via sol-gel process,and X-ray diffraction(XRD),UV-visble absorption spectra techniques were applied to investigated thes phase structure and spectrum properties as-synthesized samples.The influence of La3+ doping on the structure and phase transformation behaviors of anatase to rutile TiO2 powders was investigated by means of XRD.UV-vis adsorption spectroscopy revealed that La-doped TiO2 has a strong a adsorption band and the absorption edge were red-shifted compartion with pure TiO2.The experiment results of photocatalytic decomposition of methyl-organge indicated that La-doping restrained the transformation of anatase to rutile and growth of grain.Therefore,La-doping improved the TiO2 photocatalytic activity in photodegradation of methyl-organge.In addition,experiments also illustrate that the catalyst has good activity of decolor rate of Yan’an cigarette factory wastewater.

【基金】 国家自然科学基金(20773104);教育部新世纪人才支持计划基金(NCET-06-0891);教育部重点科研基金(208143);陕西省教育厅专项科研基金(07JK435);陕西省科技厅科研基金(2007-119);陕西省重点实验室重点科研基金(08JZ81,08JZ82);延安大学基金(KYQD2007010)资助项目
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2009年03期
  • 【分类号】O643.36
  • 【被引频次】4
  • 【下载频次】141
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