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石墨型C3N4的固态合成及嵌锂性能研究
Solid-state Synthesis of Graphite-like C3N4 and Its Reversible Li+ Intercalation
【摘要】 采用固态反应方法制备了石墨型C3N4.采用XRD,FTIR,XPS对产物的组成和结构进行了表征.研究了石墨型C3N4的电化学行为,并将其用作负极材料组装成锂离子电池进行测试,发现该材料具有一定的嵌锂能力,但比容量低,循环寿命短.采用少量嵌入Mg2+,Al3+的方法对石墨型C3N4进行改性,结果发现石墨型C3N4的充放电性能得到一定改善.
【Abstract】 Graphite-like carbon nitride(g-C3N4) was synthesized using a solid state method and characterized by XRD,FTIR and XPS.The electrochemical properties of the g-C3N4 were studied using both cyclic voltammetry and charge-discharge cycling.It was found that the g-C3N4 sample showed certain reversible intercalation capacity of Li+,but the capacity dropped sharply during the first few cycles.The poor reversi-bility could be ascribed mainly to the decomposition of C3N4 upon electroreduction.Modification of the g-C3N4 was performed by intercalating a little amount of Mg2+ and Al3+ into its interlayer spacing,which made slight improvement on the crystallization and the reversible Li+ intercalation of the residual g-C3N4.
【Key words】 graphite-like C3N4; solid-state synthesis; electrochemical property; lithium-ion battery; reversible lithium intercalation;
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2009年11期
- 【分类号】O611.3
- 【被引频次】22
- 【下载频次】760