【摘要】 光照下,以甲醇为氢源,以NiCl2、Ni(OAc)2或CoCl2为催化剂,1-辛烯可以发生催化转移加氢反应,得到辛烷,主要副产物为双键异构的2-辛烯和3-辛烯。综合催化剂的加氢活性和产物辛烷的选择性,NiCl2的催化效果最好,且NiCl2的催化活性在293～333K范围内随温度升高而增加。以NiCl2为催化剂,在反应体系中添加三正丁胺,于293K下反应24h,辛烷的产率由45%提高到65%,选择性由57%提高到70%。更多还原

【Abstract】 The catalytic transfer hydrogenation of 1-octene to octane was carried out by using methanol as hydrogen donor and nickel and cobalt salts（such as NiCl₂,Ni（OAc） 2 or CoCl₂） as catalysts under irradiation.The major byproducts were 2-octene and 3-octene from isomerization of CC.Among these catalysts,NiCl₂ was the most efficient in terms of octane yield and selectivity.Furthermore,the catalytic activity of NiCl₂ increased at the elevated temperature（293～333K）.It was beneficial to the hydrogenation and restrained the side-reaction by adding tri-n-butylamine into reactive system,the yield of octane was increased from 45% to 65% and the selectivity of octane improved from 57% to 70% with NiCl₂ as catalyst at 293K after 24h.更多还原