【摘要】 α-磷酸锆(α-Zr(HPO4)2·H2O,α-ZrP)、γ-磷酸锆(Zr(PO4)(H2PO4)·2H2O,γ-ZrP)及其衍生物由于在离子交换、质子传导、插层化学、催化、光化学、材料化学等领域有潜在的应用前景,因而引发了大量的研究工作。本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。更多还原

【Abstract】 α-Zirconium phosphate （α-Zr（HPO₄）₂·H₂O,α-ZrP）,γ-zirconium phosphate （Zr（PO₄）（H₂PO₄）·2H₂O,γ-ZrP） and their derivatives have attracted a lot of research attention in recent years due to their potential applications in the areas of ion exchange,proton conductivity,intercalation chemistry,catalysis,photochemistry and material chemistry. The mechanism,thermodynamics and kinetics of ion-exchange reactions between alkali,alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed,progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.更多还原