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键合纤维素手性固定相的合成及手性拆分
Preparation of covalently bonded cellulose-derived chiral stationary phase and enantioseparation
【摘要】 合成了键合型纤维素-(二苯基甲基二氨基甲酸酯/苯基氨基甲酸酯)手性固定相,并用此键合柱在流动相正己烷/异丙醇下对几种手性化合物进行了拆分,实验结果表明,此手性固定相具有一定的拆分能力。
【Abstract】 Cellulose-(diphenymethyldicarbamate/phenylcarbamate)chiral stationary phase was prepared.Four chiral compounds were enantioseparated on this stationary phase with n-hexane/isopropanol as mobile phase.The results show that this stationary phase has some discrimination ability,and the effect of isopropanol concentration in the mobile phase on separation was investigated.
【关键词】 键合多糖手性固定相;
手性拆分;
对映体;
【Key words】 bonded polysaccharide chiral stationary phase; chiral separation; chiral stationary phase;
【Key words】 bonded polysaccharide chiral stationary phase; chiral separation; chiral stationary phase;
【基金】 甘肃省科技厅自然科学基金项目资助(32S042-B25-020);甘肃省科技攻关计划项目资助(2GS064-A52-036-06);兰州交通大学“青蓝”人才工程基金项目资助
- 【文献出处】 化学工程师 ,Chemical Engineer , 编辑部邮箱 ,2009年02期
- 【分类号】O657.7
- 【被引频次】5
- 【下载频次】341