【摘要】 合成出一种新型激光敏感配合物起爆药二水合高氯酸(3-肼基-4-氨基-5-巯基-1,2,4-三唑)合钴(TACo),得率达71%;用元素分析、红外光谱等分析方法对其进行结构表征;测试了它的激光感度和部分爆炸性能,该化合物起爆药在915 nm激发波长下的50%激光起爆能量密度为39.85 J.cm-2。实验结果表明:合成过程中温度和原料粒度对反应影响较大。更多还原

【Abstract】 Laser sensitive coordination compound 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole cobalt(Ⅱ) perchlorate dihydrate(TACo) was synthesized with the yield of 71%.The structure of the obtained compound was identified by IR and elemental analysis.The laser sensitivity and part of the explosive performance were tested.The 50% fire energy density in 915 nm laser wavelength was 39.85 J·cm-2.Results show that the temperature and particle size of the samples have significant effects on the synthesis reaction.更多还原