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均匀设计法在赤磷发烟剂红外消光性能中的应用

Application of Uniform Design in Infrared Extinction Performance of Red Phosphorus Smoke Agent

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【作者】 周明善徐铭沈瑞琪闵军李澄俊

【Author】 ZHOU Ming-shan,XU Ming,SHEN Rui-qi,MIN Jun,LI Cheng-jun(School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China)

【机构】 南京理工大学化工学院

【摘要】 运用均匀设计法进行赤磷发烟剂的配方优化设计,减少了试验工作量,根据均匀设计法实验结果,通过回归分析,分别得到两组具有较强红外消光性能的赤磷发烟剂配方,一是四组分配方:包覆赤磷87%,高氯酸钾5.9%,镁粉2.5%,氟橡胶4.6%;二是五组分配方:赤磷68.8%,硝酸钾14%,镁粉8.9%,氯化石蜡3.8%,氟橡胶4.5%。实验结果表明,两组赤磷发烟剂配方在相对湿度为48%、质量浓度为1g.m-3的条件下,具有较好的红外消光效果,对8~14μm波段的红外透过率分别为12.81%、11.92%。

【Abstract】 Uniform design was used to optimize the formula design of red phosphorus smoke agent.The four-component-formula and five-component-formula of red phosphorus smoke agent were obtained by regression analysis.The optimal formula were as follows:four-component-formula(coated red phosphorus 87%,KClO4 5.9%,Mg 2.5%,fluorine rubber 4.6%);five-component-formula(red phosphorus 68.8%,KNO3 14%,Mg 8.9%,chlorinated paraffin 3.8%,fluorine rubber 4.5%).Results show that the infrared transmittance in 8-14 μm of two formula of red phosphorus smoke agent were 12.81% and 11.92% when the relative humidity is 48% and mass concentration is 1 g·m-3.

  • 【文献出处】 含能材料 ,Chinese Journal of Energetic Materials , 编辑部邮箱 ,2009年03期
  • 【分类号】TJ536
  • 【被引频次】3
  • 【下载频次】190
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