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稻壳热解特性及其动力学研究

Study on Characteristics and Kinetics of Pyrolysis Process of Rice Husk

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【作者】 王章霞陈明强王君陈明功闵凡飞

【Author】 WANG Zhang-xia,CHEN Ming-qiang,WANG Jun,CHEN Ming-gong,MIN Fan-fei (School of Chemical Engineering,Anhui University of Science and Technology,Huainan Anhui 232001,China)

【机构】 安徽理工大学化学工程学院

【摘要】 研究不同粒径的稻壳以及其在不同的升温速率下的热解特性。从TG和DTG图上可看出,粒径为0.88~0.38mm的稻壳的失重率(约60%)最大,粒径在0.08mm以下的失重率最小(约55%);随着升温速率的增加,TG和DTG曲线向高温侧移动,热流率逐渐增大,最大失重速率对应的温度升高,而最大失重速率降低。采用FWO法和Popescu法计算了稻壳热解的动力学参数并确定最佳机理函数。

【Abstract】 Pyrolysis characteristics of different size of rice husk under different heating rates were studied.Rice husk with particle size between 0.88 and 0.38 mm had maximum weight loss ratio(about 60%),while particle size below 0.08 mm minimum weight loss ratio(about 55%).With increase of heating rate,TG and DTG curve move to the high-temperature zone and heat flow rate as well as the temperature corresponding to the maximum rate of weight loss increased while the maximum rate of weight loss decreased.The methods of FWO and Popescu were used to calculate kinetics parameters of rice husk pyrolysis process and the optimal mechanism functions were determined.

【关键词】 热解特性动力学稻壳热分析
【Key words】 pyrolysiskineticsrice huskthermal analysis
【基金】 国家自然科学基金资助项目(20676002);安徽省教育厅高校省级自然科学基金资助项目(KJ2008B045);淮南市科技基金资助项目(2008018)
  • 【文献出处】 安徽理工大学学报(自然科学版) ,Journal of Anhui University of Science and Technology(Natural Science) , 编辑部邮箱 ,2009年01期
  • 【分类号】TK6
  • 【被引频次】27
  • 【下载频次】434
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