【摘要】 通过对热塑性树脂PAEK增韧BMI树脂的玻璃化转变行为,相形貌和断裂韧性,以及对采用"离位"概念增韧的T700/BMI复合材料的层间形貌及其冲击后压缩强度(CAI)的分析,研究了微结构-性能之间的关系,发现特征相分离形貌随着PAEK的含量而变化。特别探索了PAEK-BMI复相体系的相形貌与断裂韧性之间的关系,得到的断裂机理解释了复合材料层压板的分层和冲击损伤行为。有关"离位"增韧的机理、以及扩散控制的相行为等还需要继续研究。更多还原

【Abstract】 The microstructure property relationships have been studied in terms of glass transition behavior,phase morphology,and fracture toughness on thermoplastic polyetherketone with a phenolphthalein side group (PAEK) toughened bismaleimdes (BMI) resins,and in terms of interlaminar morphology and compression after impact (CAI) on the graphite fiber (T700SC),the rein-forced BMI matrix composites that are toughened with a so-called ex-situ concept,respectively. The characteristic morphology spectrum has been found to occur as the concentration of PAEK is varied. In particular,the relationship between the morphology and the fracture toughness has been explored on the PAEK-BMI blends. The fracture micromechanism has then been used to explain the delamination and impact damage behavior on the graphite laminated systems,where the morphology properties relationship held true. The complex nature of the diffusion-controlled phase behavior has also qualitatively been studied,which served as a model for understanding the ex-situ toughening concept.更多还原