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活性炭负载水合氧化铁对草甘膦吸附性能的研究

Adsorption of glyphosate from aqueous solutions by hydrous ferric oxide preloaded into activated carbon

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【作者】 葛磊王静陈欢崔皓陶仙聪郑建中

【Author】 Ge Lei1 Wang Jing1 Chen Huan1 Cui Hao1 Tao Xiancong2 Zheng Jianzhong1(1.State Key Laboratory of Pollution Control and Resources Reuse,School of the Environment,Nanjing University,Nanjing 210093,China;2.Modern Analysis Center,Nanjing University,Nanjing 210093,China)

【机构】 南京大学环境学院污染控制与资源化研究国家重点实验室南京大学现代分析中心

【摘要】 利用活性炭制备了水合氧化铁负载活性炭AC-Fe,并通过静态吸附实验研究了该材料对水溶液中草甘膦的吸附性能。研究结果表明,该负载方法可以在活性炭上嫁接72 mg/g的铁,AC-Fe对草甘膦的最大吸附容量可以达到120mg/g;AC-Fe对草甘膦的吸附量随pH的升高而降低;磷酸根对AC-Fe的吸附性能具有明显的抑制作用,原因在于它能和铁离子形成内层络合物,与草甘膦竞争材料表面的吸附位点。

【Abstract】 Hydrous ferric oxide was preloaded into an activated carbon,and glyphosate adsorption properties by this material were studied through batch tests.Results showed that 72 mg/g Fe was grafted onto AC,and the Qmax was increased to 120 mg/g.Adsorption of glyphosate by AC-Fe decreases with increasing pH.The existence of phosphate decreased glyphosate adsorption significantly because of its complexation with actived binding sites on hydrous ferric oxide.

【关键词】 活性炭水合氧化铁草甘膦吸附
【Key words】 activated carbonhydrous ferric oxideglyphosateadsorption
【基金】 国家自然科学基金资助项目(20540420542,20377021)
  • 【文献出处】 环境工程学报 ,Chinese Journal of Environmental Engineering , 编辑部邮箱 ,2009年10期
  • 【分类号】X703
  • 【被引频次】24
  • 【下载频次】559
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