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原位柱撑改性膨润土在微污染饮用水除磷中的应用研究

Applied research of in-situ pillared bentonite on removing phosphor from micro-polluted drinking water

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【作者】 王趁义袁晖韩志萍袁彩君唐铭胡娟娟

【Author】 Wang Chenyi1 Yuan Hui2 Han Zhiping1 Yuan Caijun1 Tang Ming3 Hu Juanjuan1 (1.Department of Chemistry,Huzhou Teachers College,Huzhou 313000,China;2.Anfu No.2 Middle School,Ji’an 343200,China;3.Huzhou Water Supply Company,Huzhou 313000,China)

【机构】 湖州师范学院化学系江西省安福县第二中学湖州市自来水公司

【摘要】 利用Al3+离子较易水解聚合的性质,微波辅助合成了keggin Al13原位柱撑改性膨润土(PMCs),并探究了其对微污染饮用水中磷元素的去除作用,研究表明,PMCs对磷的混凝和去除作用优于原土、工业PAC和传统的柱撑改性膨润土(CPMCs);影响除磷效果的主要因素有:搅拌时间、搅拌速度、水样的pH值以及初始浓度等,其最佳除磷条件是:在500mL10 mg/L含磷水样中加入1.5 g改性膨润土,搅拌速度为180 r/min,搅拌时间为5 h,水样pH为6~8。

【Abstract】 Making use of the character of Al3+ which is prone to hydrolysis and polymerization,the modified bentonite in-situ pillared of keggin Al13(termed as PMCs)were made by microwave radiation,and the capability of removing phosphorus with PMCs were researched.The results showed that the PMCs is better than others,such as,the raw soil,the industrial aluminium polychlorid,and the traditional pillared bentonite(CPMCs);the major factors affecting the result of removing phosphorus with PMCs are stirring time,stirring rate,pH value and initial concentration of water sample.The best conditions of removing phosphorus are: adding 1.5 g modified bentonite in 500 mL water sample of 10 mg/L phosphorus,5 h stirring time,180 r/min stirring speed,and pH 6~8.

【基金】 国家自然科学基金资助项目(30771696);浙江省自然科学基金项目(Y407318);湖州市科技计划项目(2007YZ06)
  • 【文献出处】 环境工程学报 ,Chinese Journal of Environmental Engineering , 编辑部邮箱 ,2009年08期
  • 【分类号】TU991.2
  • 【被引频次】14
  • 【下载频次】297
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