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几种试剂对硝酸根光催化脱色甲基橙的影响

Influence of several reagents on photocatalytic decolorization of methyl orange with NO3-

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【作者】 李建章冯发美蒋维东曾俊黄生田

【Author】 Li Jianzhang Feng Famei Jiang Weidong Zeng Jun Huang Shengtian (Institute of Catalysis,Departmemt of Chemistry,Sichuan University of Science and Engineering,Zigong 643000)

【机构】 四川理工学院化学系催化研究所

【摘要】 以NO3-为光催化剂,在紫外灯照射下,对甲基橙溶液进行光催化脱色。结果表明,叔丁醇、甲醇和乙醇对催化脱色反应有抑制作用;KB r和Na2SO4对脱色反应均有促进作用;而且KB r的加入量存在最佳值;Na2SO4的促进作用随Na2SO4的量的增加逐渐增强。Na2CO3的存在对甲基橙的脱色反应没有影响。K2S2O8和NO3-之间存在较强的协同作用;K IO3和NO3-之间存在相加作用;KB rO3和NO3-之间存在拮抗作用。

【Abstract】 The NO-3 was used to decolorize the methyl orange(MO) solution with ultraviolet radiation.Influence of several reagents on photocatalytic decolorization of methyl orange with NO-3 was investigated.The results indicate that t-BuOH,ethanol and methanol can press the decolorization reaction,KBr and Na 2SO 4 can promote the decolorization reaction,there is an optimal amount of KBr in this case and the effects of Na 2SO 4 increase with the concentrations,while Na 2CO 3 has no obvious influence on the decolorization reaction.The synergy between K 2S 2O 8 and NO-3 is very strong.There is no synergy between KIO 3 and NO-3,while there is inhibitation between KBrO 3 and NO-3.

【基金】 四川省教育厅重大培育项目(07ZZ020)
  • 【文献出处】 环境工程学报 ,Chinese Journal of Environmental Engineering , 编辑部邮箱 ,2009年05期
  • 【分类号】X703
  • 【被引频次】2
  • 【下载频次】102
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