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Sc:Mn:Fe:LiNbO3晶体的缺陷结构及抗光损伤能力(英文)

DEFECT STRUCTURE AND OPTICAL DAMAGE RESISTANCE OF Sc:Mn:Fe:LiNbO3 CRYSTALS

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【作者】 郑威李光滨徐玉恒

【Author】 ZHENG Wei~1 LI Guangbin~1 XU Yuheng~2(1.College of Materials Science and Engineering,Harbin University of Science and Technology,Harbin 150040;2.Department of the Applied Chemistry,Harbin Institute of Technology,Harbin 150001,China)

【机构】 哈尔滨理工大学材料科学与工程学院哈尔滨工业大学应用化学系

【摘要】 采用提拉法生长了不同Sc掺杂的Sc:Mn:Fe:LiNbO3晶体,通过紫外-可见光谱测试分析了Sc:Mn:Fe:LiNbO3晶体的缺陷结构,利用光斑畸变法表征了其抗光损伤能力。结果表明:当Sc2O3的浓度超过阈值浓度(1.5%,摩尔分数)时,Sc:Mn:Fe:LiNbO3晶体的抗光损伤能力远远高于未达到阈值浓度的晶体,其紫外-可见光谱将发生红移;当Sc2O3的浓度未达到阈值浓度时,随着Sc掺量的增加.Sc:Mn:Fe:LiNbO3晶体的紫外-可见光谱将发生紫移。

【Abstract】 Sc:Mn:Fe:LiNbO3 crystals with different Sc3+doping concentrations were grown by the Czochralski method from congru- ent melts.The defect structure of the crystals were studied with ultraviolet-visible(UV-Vis)absorption spectra,and the optical dam- age resistance was characterized by the transmitted spot distortion method.In Sc:Mn:Fe:LiNbO3 crystals when the doping concentra- tion of Sc2O3 exceeds the threshold concentratin(1.5%,in mole),the optical damage resistance is much higher than in other crystals, and the absorption-edge-position of Sc:Mn:Fe:LiNbO3 crystals has a red-shift.When the doping concentration of Sc2O3 cannot reach the threshold concentration,the absorption-edge-position of Sc:Mn:Fe:LiNbO3 crystals shifts to violet with the increase of doping content of Sc2O3-doped increased.

  • 【文献出处】 硅酸盐学报 ,Journal of the Chinese Ceramic Society , 编辑部邮箱 ,2009年01期
  • 【分类号】O77
  • 【下载频次】101
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