【摘要】 采用分子自组装印迹技术合成了一种新的对甲胺磷农药分子有高度选择性的分子印迹聚合物。在预聚合阶段,通过1H NMR,FTIR和UV光谱法研究了分子印迹聚合物的形成机理。结果表明模板分子和功能单体通过协同氢键作用形成1∶2型氢键配合物,配合物稳定常数K=2.894×106L2.mol-2,稳定性好。运用红外光谱法研究了印迹聚合物对模板分子的特异性识别作用,进一步表明印迹聚合物通过协同氢键作用特异性地识别模板分子。更多还原

【Abstract】 A new methamidophos-specific molecularly imprinted polymer(MIP) was synthesized based on non-covalent interaction.The complexes formed between MAP and MAA were evaluated by 1H NMR,FTIR and UV spectrometry.The MAP-MAA complexes of 1∶2 mole ratio were obtained by cooperative hydrogen bonding and the complexes possessed better stabilization(K=2.894×106 L2·mol-2).The Infrared spectrometry differences of the MIPs before and after saturated with MAP further indicated that there were carboxyl functional groups in the MIP,which could interact with the template by cooperative hydrogen bonding specifically.更多还原