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羧基淀粉接枝聚合物对重金属离子的吸附等温方程

Sorption Isothermal Equation of Carboxyl-Containing Starch Graft Polymer for Some Heavy Metal Ions

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【作者】 张力刘玲玲李康兰王桂良

【Author】 ZHANG Li,LIU Ling-ling,LI Kang-lan,WANG Gui-liang(Experimental and Teaching Institute of Green Chemistry,Lanzhou City University,Lanzhou 730070,China)

【机构】 兰州城市学院绿色化学实验与教学研究所

【摘要】 通过化学反应过程将丙烯腈接枝到高交联淀粉上,接枝产物再经皂化水解制得不溶性羧基淀粉接枝聚合物(简称羧基淀粉).研究了羧基淀粉吸附重金属离子的容量,结果表明,吸附量随吸附平衡浓度的变化规律,遵从Q/Qmax=ac/(1+ac)方程.

【Abstract】 Water-insoluble carboxyl-containing starch graft polymer(carboxyl-containing starch) was prepared by grafting acrylonitrile onto highly cross-linked starch,followed by base saponification to convert nitrile group into a mixture of carboxamide and carboxylate groups.The sorption amount properties of carboxyl-containing starch for several heavy metal ions have also been studied systematically.It is shown that the relationship between the sorption amount and equilibrium concentration complies completely with the following sorption isothermal equation Q/Qmax=ac/(1+ac).

【基金】 甘肃省教育厅科研项目(0511B-02)
  • 【文献出处】 甘肃科学学报 ,Journal of Gansu Sciences , 编辑部邮箱 ,2009年02期
  • 【分类号】O647.31
  • 【被引频次】4
  • 【下载频次】277
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