节点文献
一种新型四硫富瓦烯衍生物的合成与表征
Synthesis and Characterization of a New Tetrethiafulvalence Derivatives
【摘要】 以二硫化碳和金属钠为基础物质合成了四硫富瓦烯(TTF)锌的配合物(TTF)Zn(NBu4)2。利用该化合物与苯甲酰氯反应得到的稳定化合物C17H10O2S5在甲醇钠溶液中与2,3-二溴丙醇反应成功合成出目标化合物(一种新配体),其化学组成为C6H6OS5。利用IR谱、1HNMR谱及元素分析对此化合物进行了表征。
【Abstract】 A new tetrathiafulvalence derivatives En(NBu4)2 was synthesized with carbon disulfide and sodium.This compound was reacted with 2,3-dibrimide-1-butyl-propyl-alcobol,and a new coordination complex C17H10O2S5 was synthesized and the complex was characterized by IR, 1HNMR and element analysis.
【关键词】 新型四硫富瓦烯衍生物;
合成;
表征;
【Key words】 New Tetrathiafulvalence Derivatives; Synthesis; Characterization;
【Key words】 New Tetrathiafulvalence Derivatives; Synthesis; Characterization;
- 【文献出处】 光谱实验室 ,Chinese Journal of Spectroscopy Laboratory , 编辑部邮箱 ,2009年05期
- 【分类号】O621.2
- 【下载频次】126