【摘要】 采用电化学聚合法制备聚四氨基钴酞菁修饰电极,并用循环伏安法研究其对氧的电催化作用.实验表明,修饰电极在pH=5柠檬酸-柠檬酸钠缓冲溶液中,峰电流与氧质量浓度在1.6～8.0mg/L范围内呈线性关系,平行6次测定氧体积分数RSD=1.7%,回收率为98.02%～111.68%.更多还原

【Abstract】 s :Polymeric cobalt tetraaminophthalocyanine was prepared by electropolymerization and the electrochemistry properties toward dioxygen reduction were studied using cyclic voltammetry.The result indicated that the modified electrode was in pH=5 citric acid-sodium citrate buffer solution,the peak current was proportional to the concentration of dissolved oxygen in the range from 1.6～8.0 mg/L,for six parallel measurements of dissolved oxygen,the relative standard was found to be 1.7%,the rate of recovery was between 98.02%～111.68%.更多还原