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Cis-[Pt(NH3)2(H2O)2](NO3)2与1,1-环丁烷二羧酸钠形成的一种新的Pt(Ⅱ)配合物(英文)
A Novel Insoluble Pt(Ⅱ)Complex Produced by the Reaction of cis-[Pt(NH3)2(H2O)2](NO3)2 and Sodium 1,1-cyclobutanedicarboxylate
【摘要】 从Cis-[Pt(NH3)2(H2O)2](NO3)2与1,1-环丁烷二羧酸钠的化学反应中,分离出一种新的Pt(Ⅱ)配合物,通过元素分析、红外光谱,质谱和高效液相色谱的分析测试,初步推测结构为顺式-四氨-μ-二(1,1-环丁烷二羧酸根-O1,O2)合二铂的新化学结构式。
【Abstract】 Besides carboplatin,a novel insoluble Pt(Ⅱ)complex was obtained by the chemical reaction between cis-[Pt(NH 3)2(H 2O)2](NO 3)2 and sodium 1,1-cyclobutanedicarboxylate with a yield of ca.3.6% based on platinum.Its chemical structure was studied by elemental analysis,IR,MS-FAB + and HPLC.The results suggested that the complex possess a novel structure of cis-tetraammine-μ-di(1,1-cyclobutanedicarboxylate-O 1,O 2)diplatinum(Ⅱ).
【关键词】 配位化学;
铂(Ⅱ);
双核配合物;
合成;
【Key words】 coordination chemistry; platinum(Ⅱ); dinulear complex; synthesis;
【Key words】 coordination chemistry; platinum(Ⅱ); dinulear complex; synthesis;
【基金】 Yunnan Provincial Scientific Development Programme(2008CC020);Science Foundation of P.R.of China(20861004)
- 【文献出处】 贵金属 ,Precious Metals , 编辑部邮箱 ,2009年02期
- 【分类号】O641.4
- 【被引频次】3
- 【下载频次】131