【摘要】 环糊精具有良好的生物相容性和环境友好性,并且来源丰富、价格低廉,其在高分子合成领域中的应用越来越受到关注。研究表明,难溶于水的有机单体与环糊精形成的复合物可以直接在水相中通过自由基成功地引发聚合。这一方面使反应过程更加绿色化,减轻污染;另一方面,通过调整配方和工艺,可以进一步简化流程,控制产物结构,提高产物质量。本文从环糊精及环糊精/单体复合物分子结构出发,较为系统的综述了近些年来环糊精在聚合反应中的应用成果。更多还原

【Abstract】 Cyclodextrins(CD),characterized by its biocompatibility,environmental amity,and low price,has been used in many fields.In recent years,its application in polymer chemistry attracts researchers attention.Generally,insoluble organic monomer can form complex with cyclodextrins that can be polymerized in water by free radicals,without any organic solvent and surfactant.So,one side,the reaction could be more green;other side,the process could be more simple,the structure of the product more controllable,and the quality better.According to the structure of the monomer and the monomer/cyclodextrin complex,this article reviewed applications of cyclodextrin in the polymerization,including the changes of polymerization process,reaction parameters,structures and properties of the products,and the polymerization mechanism which is very important.更多还原