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聚硅氧烷与丙烯酸酯弹性体的制备及性能
Performances and Preparation of Polysiloxane and Acrylate Elastomer
【摘要】 用含乙烯基的硅氧烷单体和八甲基环四硅氧烷与丙烯酸酯共聚,制备出不同硅含量的硅丙乳液,研究了有机硅含量对微乳液聚合过程和乳胶膜透明性、交联度、热性能和力学性能的影响。结果表明,随着硅含量的增加,综合性能均得到改善,当有机硅单体用量达20%时为最佳配比。
【Abstract】 The elastic silicone-acrylate emulsions of different silicone content were prepared using vinyl siloxanes and grafting siloxanes.The effects of silicone content on the process of microemulsion polymerization and transparence,cross-linking degree,heat resistance and the mechanical properties of latex film were studied.The results show that the general performances of silicone-acrylate latex film are improved with the increase of silicone content in monomers,and the latex film has excellent performance when the silicone content gets to 20% of total monomers.
【关键词】 聚硅氧烷单体;
乳液聚合;
交联度;
【Key words】 polysiloxane monomer; emulsion polymerization; cross-linking degree;
【Key words】 polysiloxane monomer; emulsion polymerization; cross-linking degree;
- 【文献出处】 高分子材料科学与工程 ,Polymer Materials Science & Engineering , 编辑部邮箱 ,2009年02期
- 【分类号】TQ334.9
- 【被引频次】15
- 【下载频次】423