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一种新型磷光材料的电致发光特性研究

Study on electroluminescence characteristic of a new phosphorescent materials

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【作者】 张迪杨刚文雯李璐于军胜蒋泉王军钟建朱凤稚骆开均谢运徐玲玲

【Author】 ZHANG Di1,YANG Gang1,WEN Wen1,LI Lu1,YU Jun-sheng1,JIANG Quan1,WANG Jun1,ZHONG Jian1,ZHU Fengzhi1,LUO Kai-jun2,XIE Yun2,XU Lin-lin2(1.Key Display Laboratory of Science and Technology of Sichuan,School of Optoelectronic Information,University of Electronic Science and Technology of China,Chengdu,610054,China;2.Institute of Chemistry and Materials,Sichuan Normal University,Chengdu,610081,China)

【机构】 电子科技大学光电信息学院四川省显示科学与技术重点实验室四川师范大学化学与材料学院

【摘要】 设计与合成了一种基于Pt配合物的新型磷光材料(ppy)Pt(bcam),用其制备了相应的磷光器件,器件的结构为ITO/NPB(50 nm)/CBP(15 nm)/(ppy)Pt(bcam)(0.3-2.0 nm)/CBP(15 nm)/BCP(10 nm)/Alq3(20 nm)/Mg:Ag(200 nm),并对器件的相关特性进行了研究。(ppy)Pt(bcam)磷光器件的最大发光波长为625 nm,器件的最大发光波长随驱动电压变化很小,显示了该器件磷光特性非常稳定;磷光发光层厚度为0.5 nm在驱动电压为24.25 V时亮度达到8 755 cd/m2,电流密度为499 A/m2时得到最大的电流效率3.33 cd/A。

【Abstract】 A new phosphorescent material based on the platinum complex has been synthesized.The phosphorescent devices have been fabricated by adopting the ultrathin film technology.The device structure is ITO/NPB(50 nm)/CBP(15 nm)/(ppy)Pt(bcam)(0.3-2.0 nm)/CBP(15 nm)/BCP(10 nm)/ Alq(20 nm)/Mg:Ag(200 nm).The relative characteristics of the devices are studied.The peak at 625 nm is the emission spectrum of(ppy)pt(bcam),and the emission spectrum of(ppy)pt(bcam) almost has no change at different driving voltage,it is obviously that the electro-phosphorescent characteristics of(ppy)pt(bcam) are very stable.The highest brightness of phosphorescent device,whose phosphor layer thickness is 0.5 nm,is 8 755 cd/m2 under the driving voltage of 24.25 V,the highest current efficiency is 3.33 cd/A at the current density of 499 A/m2.

【基金】 国家自然科学基金资助项目(20472060)
  • 【文献出处】 光电子.激光 ,Journal of Optoelectronics.Laser , 编辑部邮箱 ,2009年06期
  • 【分类号】TN383.1
  • 【被引频次】15
  • 【下载频次】302
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