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基于含羟基聚芳醚砜的有机-无机杂化材料的制备

Preparation of Organic-inorganic Hybrid Materials Based on a Hydroxyl-containing Polyethersulfone

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【作者】 陈文慧刘佰军杨延华岳喜贵井丽巍郭梅梅孙小红高连勋姜振华

【Author】 CHEN Wen-Hui1,2,LIU Bai-Jun1,YANG Yan-Hua1,YUE Xi-Gui1,JING Li-Wei1,GUO Mei-Mei1,SUN Xiao-Hong2,GAO Lian-Xun2,JIANG Zheng-Hua1(1.Alan G.MacDiarmid Institute,Jilin University,Changchun 130012,China;2.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)

【机构】 吉林大学麦克德尔米德实验室中国科学院长春应用化学研究所

【Abstract】 A novel aromatic polyethersulfone bearing a(3-methoxy)phenyl group(PPES-OMe)was synthesized via an aromatic nucleophilic substitution reaction.A hydroxyl-containing polyethersulfone(PPES-OH)was successfully obtained via a demethylation reaction of PPES-OMe.A series of nano-hybrid materials could be prepared with sol-gel method and FTIR results suggested the chemical bond formed between the hydroxyl group of PPES-OH and TEOS.Nano-size SiO2 particles were observed to disperse uniformly in the polyethersulfone matrix by SEM.It was found that all the films based on these materials were flexible.

【基金】 国家自然科学基金(批准号:50973040)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2009年12期
  • 【分类号】O631.3
  • 【被引频次】3
  • 【下载频次】177
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