【摘要】 通过水热方法合成了超分子化合物(Hfcz)3(PMo12O40).3H2O.单晶X射线衍射分析表明化合物结晶于三方晶系,P-3c空间群.化合物中的两种亚单元通过氢键作用形成了3D超分子结构.化合物堆积形成了孔道结构.此外,循环伏安法研究结果表明了化合物展示三个连续的双电子还原过程.更多还原

【Abstract】 The supramolecular compound of(Hfcz)3(PMo12O40)·3H2O has been isolated by hydrothermal method.X-ray single crystal diffraction analysis reveals that the compound crystallizes in trigonal and space group of P-3c.There are two kinds of subunits in the unique unit which are linked each other through hydrogen bonds to generate a 3D supramolecular structure with porous features.In addition,the electrochemical property of the compound has been researched using cyclic voltammograms,which shows three consecutive two-electron processes.更多还原