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离子交换法纳米Cu2O的制备及光催化性能的研究

Preparation of Cu2O Nanoparticle by Ion Exchange Method and Its Photocatalytic Performance

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【作者】 姚红霞嘎日迪杨保军李国晓照日格图

【Author】 YAO Hong-xia1,Garidi1,YANG Bao-jun2,LI Guo-xiao1,B.Zhaorigetu1(1.Laboratory of Natural Gas Chemistry & Material Science,Inner Mongolia Normal University,Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials,Hohhot 010022,China;2.Inner Mongolia Autonomous Science and Technology Overseas Exchange Center,Hohhot 010010,China)

【机构】 内蒙古师范大学天然气化工与材料科学实验室内蒙古自治区功能材料物理与化学重点实验室内蒙古自治区对外科技交流中心

【摘要】 采用强酸性阳离子交换树脂(R─H),以CuSO4.5H2O为原料,制备出R2─Cu型阳离子交换树脂,R2─Cu型阳离子交换树脂与酒石酸钾钠进行离子交换得到Cu(OH)2,再用葡萄糖还原制得Cu2O纳米粒子,用IR、XRD、BET、TEM等手段对样品进行了表征,并以催化罗丹明B为模拟染料,日光(4月晴天,T=15~25℃)为光源,在自制的无色透明的玻璃反应器进行光催化降解反应,考察了Cu2O纳米粒子的催化性能.

【Abstract】 Using the strong acid ion-exchange resin(R─H) and CuSO4·5H2O as raw material,the R2─Cu ion-exchange resin was prepared,then Cu ion on the R2─Cu ion-exchange resin was exchanged with the potassium sodium in tartrate to obtain Cu(OH)2,and then the Cu(OH)2 was reduced to Cu2O nanoparticle by the glucose.The product was characterized by IR,XRD,BET,TEM.The photocatalytic behavior of the Cu2O to degradation of rhodamine B was investigated.It was found that 100mL(pH =6) 50mg L-1 rhodamine B nearly completely degraded under the solar light(in April cloudless day,6h,T=15~25 ℃),the existence of 0.4 g Cu2O and 1mL 30% H2O2.

【关键词】 离子交换法纳米Cu2O光催化
【Key words】 Ion-exchange methodCu2O nanoparticlePhotocatalysis
【基金】 国家科学技术部国际科技合作重点项目(120121)
  • 【文献出处】 分子催化 ,Journal of Molecular Catalysis , 编辑部邮箱 ,2009年02期
  • 【分类号】O643.36;X791
  • 【被引频次】13
  • 【下载频次】355
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