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共混条件对功能化聚异丁烯-蒙脱土复合物改性聚丙烯性能的影响

Influence of blend conditions on the mechanical properties of functionalized polyisobutene-montmorillonite/polypropylene composites

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【作者】 邹恩广曲佳燕王鉴闫卫东

【Author】 ZOU Enguang1,2,QU Jiayan3,WANG Jian1,YAN Weidong3(1.Daqing Petroleum Institute,Daqing 163318,China;2.Daqing Research Center of Petrochemical Engineering Research Institute,Petro China,Daqing 163714,China;3.Institute of Polymer Science and Engineering,Hebei University of Technology,Tianjin 300130,China)

【机构】 大庆石油学院化学化工学院中国石油石化研究总院大庆化工研究中心河北工业大学高分子科学与工程研究所

【摘要】 制备了功能化聚异丁烯-蒙脱土复合物改性的聚丙烯复合材料。考察了活化剂、加工温度等因素对改性聚丙烯性能的影响。通过扫描电镜观察了蒙脱土在改性聚丙烯中的分散效果。实验结果表明,功能化聚异丁烯-蒙脱土复合物可以较好地分散在聚丙烯中,当其用量为4 wt%、活化剂用量为蒙脱土的1 wt%时,制备的聚异丁烯-蒙脱土/聚丙烯复合材料的模量为2280 MPa、冲击强度为63 J/m,回缩率为0.5%,各项指标均好于未改性的聚丙烯树脂。分散在聚丙烯中的蒙脱土尺寸约为1μm。

【Abstract】 The composites of low molecular weight functionalized polyisobutene with montmorillonite were prepared as one of blend compatibilizers for improving the mechanical properties of polypropylene.The influences of active agent and blend temperature on the mechanical properties of the polyisobutene-montmorillonite/polypropylene composites were investigated.The SEM and TEM images of montmorillonite in the polypropylene matrix were observed.The results reveal that the montmorillonite disperses well in the polypropylene matrix because of the effect of the functionalized polyisobutene and the active agent.When 4 wt% montmorillonite and 1 wt%(of montmorillonite) active agent are used in the composites,the properties of polyisobutene-montmorillonite/polypropylene composite,such as modulus of 2280 MPa, impact strength of 63 J/m and recovery ratio of 0.5%,are obviously better than those of the pure polypropylene.The size of montmorillonite dispersed in the polypropylene matrix is about 1μm.

【基金】 中国石油股份公司研究项目(KY-05-11)
  • 【文献出处】 复合材料学报 ,Acta Materiae Compositae Sinica , 编辑部邮箱 ,2009年02期
  • 【分类号】TB332
  • 【被引频次】8
  • 【下载频次】263
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