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镁合金表面电弧喷涂金属耐蚀涂层性能研究

PERFORMANCE OF ELECTRIC ARC SPRAYED COATINGS ON MAGNESIUM ALLOY

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【作者】 王洪涛贾鹏林晓娉张建军李贝陈淼

【Author】 WANG Hong-tao1,JIA Peng2,LIN Xiao-ping1,ZHANG Jian-jun1,LI Bei1,CHEN Miao31.College of Material Sinence and Engineering,Hebei University of Tecnology,Tianjin 300130;2.College of Science,China University of Civil Aviation,Tianjin 300130;3.Jilin Vocational College of Industry and Technology,Jilin 132013

【机构】 河北工业大学材料科学与工程学院中国民航大学理学院吉林工业职业技术学院化学工程系

【摘要】 采用电弧喷涂方法,在AZ91D镁合金表面制备了NiCrAl、Al金属耐蚀涂层.利用扫描电镜分析、熱震实验、盐水浸泡实验、极化曲线等手段研究了涂层的结合强度和耐蚀性能.结果表明:金属涂层与基体结合紧密,孔隙率为9.68%,在350℃反复热震30次涂层表面未出现裂纹、翘起、脱落现象;NiCrAl、Al金属涂层在3.65%NaCl+5%H2SO4水溶液腐蚀介质中均表现出良好的钝化现象,其钝化区间分别为-0.3 V~0.6 V和0.2 V~0.7 V,Al涂层的工作电流为0.38 A,而NiCrAl涂层的工作电流仅为0.043 A.

【Abstract】 Coatings of NiCrAl and aluminum were prepared on the surface of AZ91D magnesium alloy by electric arc spraying.The surface and cross-sectional morphology the coatings were observed by SEM,the bond strength and the corrosion performance of the coatings were also examined.The results showed that the coating possessed a good bonding to the substrate and the porosity of the coating was 9.68%.The flaws such as crack,tilting and spall off didn′t occur after 30 cycles of thermal-shock from 350℃ to ambient temperature.The anodic polarization curves indicated that the coatings of NiCrAl and aluminum metal all exhibited well passivation behavior in a 3.65%NaCl+5%H2SO4 aqueous solution.The passivation intervals were-0.3~0.6 V and 0.2~0.7 V,correspondingly the corrosion currents were 0.38 A and 0.043 A respectively for the coatings of aluminum and NiCrAl.

  • 【文献出处】 腐蚀科学与防护技术 ,Corrosion Science and Protection Technology , 编辑部邮箱 ,2009年03期
  • 【分类号】TG174.44
  • 【被引频次】7
  • 【下载频次】243
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