【摘要】 利用中温水热技术合成了一种新型的三维无机-有机杂化化合物[Zn(4,4′-bipy)(2,2′-dpa)]n(4,4′-bipy=4,4′-联吡啶,2,2′-dpa=2,2′联苯二甲酸),并测定了该化合物晶体结构.结果表明:该化合物属于单斜晶系,C2/c空间群;晶胞参数a=2.0178(4)nm,b=0.95049(19)nm,c=1.1421(2)nm,α=90°,β=117.11(3)°,γ=90°,V=1.9498(7)nm3,Z=8,R1=0.0439,wR2=0.1307.更多还原

【Abstract】 A new three-dimensional inorganic-organic hybrid complex:[Zn(4,4′-bipy)(2,2′-dpa)]n,was synthesized by mild hydrothermal techniques,and the crystal structure was determined.The complex crystallized in the monoclicnic space group C 2/c,with a=2.0178(4) nm,b=0.95049(19) nm,c=1.1421(2) nm,α=90°,β=117.11(3)°,γ=90°,V=1.9498(7) nm3,Z=8,R1=0.0439,wR2=0.1307.更多还原