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热镀锌钢材的电偶腐蚀行为-划痕型缺陷

Wire beam electrode technique for investigating galvanic corrosion behavior of hot-dip galvanized steel-scratch defect

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【作者】 张大磊王伟李焰

【Author】 ZHANG Dalci~(1,2) WANG Wei~3 LI Yan~(1**) 1.Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071 2.Graduate School of the Chinese Academy of Sciences,Beijing 100039 3.College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100

【机构】 中国科学院海洋研究所中国科学院研究生院中国海洋大学化学化工学院

【摘要】 使用锌-碳钢异材质丝束电极技术,模拟并研究了锌/钢电偶腐蚀不同阶段的电位和电流密度的空间分布.结果表明,在锌丝与钢丝面积比为10:1的情况下,锌丝能给钢丝提供足够的阴极保护,且锌丝之间存在明显的电位、电流分布不均现象;钢丝之间也存在电化学参数分布不均现象,而且在受到保护的同时钢丝表面有氢析出.

【Abstract】 In order to obtain the spatial distribution and its variation with time during the galvanic corrosion of hot dip galvanized steel if scratches occurred in the zinc coating,the heterogeneous wire beam electrode composed of zinc and mild steel wires was developed,and then the potential and current distributions of this electrode were acquired at different time.The results showed that zinc wires can provide enough cathodic protection to steel wires in seawater when surface area of zinc wires is ten times that of steel wires.The potential and current distributions were inhomogeneous among the zinc wires. The similar heterogeneous phenomenon also presented among the steel wires,and the hydrogen evolution occurred on their surfaces.

【基金】 国家自然科学基金40576038;山东省博士基金2006BS07008;山东省自然科学基金Y2008E09资助项目~~
  • 【文献出处】 材料研究学报 ,Chinese Journal of Materials Research , 编辑部邮箱 ,2009年04期
  • 【分类号】TB304
  • 【被引频次】29
  • 【下载频次】338
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