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料浆浸渗法结合CVI制备3D C/SiC-TaC复合材料及其烧蚀性能研究

Preparing of 3D C/SiC-TaC Composites Using Slurry and CVI Method and Research on Anti-ablation Property

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【作者】 谢翀博徐永东王毅张立同成来飞王一光童长青

【Author】 XIE Chong-bo,XU Yong-dong,WANG Yi,ZHANG Li-tong,CHENG Lai-fei,WANG Yi-guang,TONG Chang-qing(National Key Laboratory of Thermostructure Composite Materials,Northwestern Polytechnical University,Xi’an 710072,China)

【机构】 西北工业大学超高温结构复合材料实验室

【摘要】 采用含1μmTaC微粉4%(体积分数)的料浆向10mm厚的3D碳纤维预制体中引入TaC,得到微粉含量高、中、低的三种预制体,CVI沉积SiC致密化后制得3DC/SiC-TaC多元基复合材料。氧-乙炔烧蚀试验后采用XRD和SEM对烧蚀产物和显微结构进行分析。结果表明:料浆法结合CVI可制备出C/SiC-TaC复合材料,高含量的TaC微粉烧蚀后形成的TaC和Ta2O5的固液混合物,能对烧蚀面进行有效包覆,有助于提高烧蚀性能。

【Abstract】 Using a kind of slurry which contains 1μm TaC fillers 4%(volume fraction) to introduce TaC fillers into 10mm thick 3D carbon fiber perform,three kind of TaC content(low,medium,high) preforms were obtained.3D C/SiC-TaC composites were prepared after densification using CVI SiC.The resultant and microstructure were studied using XRD and SEM after oxygen-acetylene flame test.The results showed that this joint method could prepare C/SiC-TaC composites,the high content TaC fillers were oxided into TaC and Ta2O5 which were a solid and liquid mixture,this mixture could effectively cover the ablation surface and promote anti-ablation poperty.

【关键词】 料浆法3DC/SiC-TaC烧蚀性能
【Key words】 slurry method3D C/SiC-TaCanti-ablation property
【基金】 国家自然科学基金(50672076)
  • 【文献出处】 材料工程 ,Journal of Materials Engineering , 编辑部邮箱 ,2009年07期
  • 【分类号】TB332
  • 【被引频次】9
  • 【下载频次】337
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