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PEG/PU多孔相变膜的相容性及热学性能分析

Analysis of Compatibility and Thermal Properties of PEG/PU Phase Change Membrane with Porous Structure

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【作者】 阮汝平谢慧方于伟东

【Author】 RUAN Ruping1,XIE Huifang1,YU Weidong1,2(1 College of Textile and Material,Wuhan University of Science and Engineering,Wuhan 430073;2 College of Textile,Donghua University,Shanghai 200051)

【机构】 武汉科技学院纺织与材料学院东华大学纺织学院

【摘要】 通过共混法制备了PEG/PU多孔相变膜,用DSC差示扫描量热法和热重法对其进行了测试,讨论了PEG/PU共混溶液的相容性、相变膜的相变行为以及其热学稳定性。实验结果表明,PU和PEG溶液具有较好的相容性;PEG/PU相变膜中PEG相转变存在滞后性,且热焓明显降低;随着PEG含量的增加,多孔膜的热稳定性有所提高。

【Abstract】 The phase change material of PEG/PU with porous membrane structure is prepared by the blending method,and it is measured by DSC and TG.The compatibility of the blended PEG/PU,phase change behavior and thermal stability of phase change membrane are discussed.The result shows that there is the good compatibility of the blended PU/PEG,and there is the PEG phase transition with hysteresis in the membrane of PEG/PU with the enthalpy decreasing obviously.With the PEG content increasing,the thermal stability of porous membrane is increased.

【关键词】 聚乙二醇聚氨酯相变焓相容性
【Key words】 PEGPUphase change enthalpycompatibility
【基金】 2005年湖北省自然科学基金项目(2005ABA015);2005年湖北省教育厅重点项目(D200517012)
  • 【分类号】TB383.2
  • 【被引频次】1
  • 【下载频次】271
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