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溶剂抽提对刺槐热诱导变色的影响

Effects of solvent extraction on the heat-induced discoloratin of locust(Robinia pseudoacacia) wood.

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【作者】 陈瑶樊永明高建民

【Author】 CHEN Yao;FAN Yong-ming;GAO Jian-min.College of Materials Science and Technology,Key Laboratory of Beijing for Wood Science and Engineering,Key Laboratory of Wood Materials Science & Application of Ministry of Education,Beijing Forestry University,100083,P.R.China.

【机构】 北京林业大学材料科学与技术学院,木材科学与工程北京市重点实验室,木质材料科学与应用教育部重点实验室

【摘要】 为探讨刺槐木材受热后颜色变异的原因,比较了蒸馏水、乙醇、丙酮、1-4二氧六环、氯仿、乙醚及正己烷等7种溶剂抽提对木粉颜色的影响;并对抽提后木粉热处理后的颜色变化进行了色度指数分析。结果表明:极性溶剂抽提可除去相当数量的易于受热改变结构而变色的成分,对刺槐颜色影响大。其中,二氧六环能够抽提出刺槐中较多有色物质和诱发刺槐木材热变色的物质;经二氧六环抽提后刺槐木粉明度最大,受热后明度和红绿轴色品差及总色差变化最小。表明二氧六环可作为研究木材热变色机理的理想溶剂。

【Abstract】 In order to makde clear the reasons of discoloration of locust(Robinia pseudoacacia) wood during a heating treatment,the authors evaluated effects of extraction with seven kinds of solvents,distilled water,ethanol,acetone,dioxane, chloroform,ether and hexane,on the discoloration of locust.An analysis of chromaticity indices on the changes of heat-treated wood flours after extraction showed that polar solvents could easily extract the colored extractives and those liable to discolor in the heating treatment,and had a marked effect on the wood color.Dioxane could extract many colored substances and induce discoloration of wood.In addition,after extracted by dioxane,the brightness of locust meal is the highest,and the variations of ΔL~*,Δa~*,Δb~* and ΔE~* is the smallest after the heating treatment.The results indicate that dioxane is an ideal solvent in the research of wood discoloration mechanism.

【关键词】 刺槐变色抽提二氧六环
【Key words】 Robinia pseudoacaciadiscolorationextractiondioxane
【基金】 国家自然科学基金项目(30671633)
  • 【文献出处】 北京林业大学学报 ,Journal of Beijing Forestry University , 编辑部邮箱 ,2009年S1期
  • 【分类号】S781
  • 【被引频次】18
  • 【下载频次】167
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